Improvement of numerical modeling of the fire reaction of solid materials. Application to fire safety engineering studies

the objective of the PhD is to improve the FDS code so that it can better describe the reaction processes to fire that take place. This work is then based on experimental tests at different scales of work, then correlated, to the development and validation of the numerical code:

• To determine experimentally the thermo-physical properties of the solid materials studied and necessary as input data of the numerical models.

Identification of the data required for the numerical models for the planned calculation code (SDS), quantification of the number of parameters and the intended operating range (combustion, pyrolysis).

Determination within Pprime in thermogravimetric analyzer (TGA), in differential scanning calorimetry (DSC) and in cone calorimeter, of the thermo-physical properties of the studied materials: thermal conductivity, specific heat and density (k, ρ, Cp), reaction enthalpies and kinetic parameters from mass loss, mass loss rate, temperature and energy data.

• Experimentally characterize thermal decomposition, ignition and flame propagation processes, identify key processes.

From small and medium scale tests, the processes of thermal decomposition (loss of mass, rate of mass loss and temperature in the solid) and combustion (ignition time, rate of heat release, temperatures in the gases) are characterized for different experimental conditions implemented. On a larger scale, in radiant panel (Pprime), the processes of ignition and flame propagation are studied, whether they are co-current or counter-current, vertical or horizontal. This analysis is complemented by large-scale tests conducted at Efectis' facilities.

-    Develop numerical models to improve prediction capability.

From the previous phases, pyrolysis models are developed and validated on an increasing scale, by comparison of experimental and numerical results: determination and optimization of kinetic mechanisms, verification and validation of design codes by material and scale. Once the pyrolysis model is validated at all scales, it is used by the partners to better describe the flame propagation processes, with an optimization of the description of heat transfers, flame/wall interaction, combustion kinetics, etc. The digital simulation expertise of both partners is thus mobilized.

Funding category: Contrat doctoral

PHD title: PhD of université de Poitiers
PHD Country: France